Department of Chemistry and Texas Center for Superconductivity, University of Houston, Houston, TX 77204-5003, USA.
Int J Mol Sci. 2013 Jul 31;14(8):15977-6009. doi: 10.3390/ijms140815977.
The tremendous interest in magnetic nanoparticles (MNPs) is reflected in published research that ranges from novel methods of synthesis of unique nanoparticle shapes and composite structures to a large number of MNP characterization techniques, and finally to their use in many biomedical and nanotechnology-based applications. The knowledge gained from this vast body of research can be made more useful if we organize the associated results to correlate key magnetic properties with the parameters that influence them. Tuning these properties of MNPs will allow us to tailor nanoparticles for specific applications, thus increasing their effectiveness. The complex magnetic behavior exhibited by MNPs is governed by many factors; these factors can either improve or adversely affect the desired magnetic properties. In this report, we have outlined a matrix of parameters that can be varied to tune the magnetic properties of nanoparticles. For practical utility, this review focuses on the effect of size, shape, composition, and shell-core structure on saturation magnetization, coercivity, blocking temperature, and relaxation time.
人们对磁性纳米粒子(MNPs)表现出了浓厚的兴趣,这反映在已发表的研究中,这些研究涵盖了从独特纳米粒子形状和复合结构的新型合成方法,到大量 MNP 表征技术,最后到它们在许多生物医学和基于纳米技术的应用中的应用。如果我们将相关结果组织起来,将关键磁性与影响磁性的参数相关联,那么从这大量研究中获得的知识将变得更加有用。调整 MNPs 的这些特性将使我们能够针对特定应用定制纳米粒子,从而提高其有效性。MNPs 表现出的复杂磁行为受许多因素的影响;这些因素可能会改善或不利地影响所需的磁性。在本报告中,我们概述了一个可以改变的参数矩阵,以调整纳米粒子的磁性。为了实际应用,本综述重点介绍了尺寸、形状、组成和壳-核结构对饱和磁化强度、矫顽力、阻塞温度和弛豫时间的影响。