Department of Chemistry, Yonsei University, Seoul 120-749, Korea.
Nano Lett. 2012 Jul 11;12(7):3716-21. doi: 10.1021/nl301499u. Epub 2012 Jun 21.
With the aim of controlling nanoscale magnetism, we demonstrate an approach encompassing concepts of surface and exchange anisotropy while reflecting size, shape, and structural hybridization of nanoparticles. We visualize that cube has higher magnetization value than sphere with highest coercivity at 60 nm. Its hybridization into core-shell (CS) structure brings about a 14-fold increase in the coercivity with an exceptional energy conversion of magnetic field into thermal energy of 10600 W/g, the largest reported to date. Such capability of the CS-cube is highly effective for drug resistant cancer cell treatment.
为了控制纳米尺度的磁性,我们展示了一种包含表面和交换各向异性概念的方法,同时反映了纳米粒子的尺寸、形状和结构杂化。我们观察到,在 60nm 时,立方体的磁化值高于球体,矫顽力最高。它与核壳(CS)结构的杂交带来了矫顽力的 14 倍的增加,同时具有 10600 W/g 的异常磁场到热能的能量转换,这是迄今为止报道的最大能量转换。CS-立方体的这种能力对于治疗耐药癌细胞非常有效。