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在单层石墨烯电极上实现高效、明亮的有机发光二极管。

Efficient and bright organic light-emitting diodes on single-layer graphene electrodes.

机构信息

IBM T.J. Watson Research Center, 1101 Kitchawan Road, Yorktown Heights, New York 10598, USA.

出版信息

Nat Commun. 2013;4:2294. doi: 10.1038/ncomms3294.

Abstract

Organic light-emitting diodes are emerging as leading technologies for both high quality display and lighting. However, the transparent conductive electrode used in the current organic light-emitting diode technologies increases the overall cost and has limited bendability for future flexible applications. Here we use single-layer graphene as an alternative flexible transparent conductor, yielding white organic light-emitting diodes with brightness and efficiency sufficient for general lighting. The performance improvement is attributed to the device structure, which allows direct hole injection from the single-layer graphene anode into the light-emitting layers, reducing carrier trapping induced efficiency roll-off. By employing a light out-coupling structure, phosphorescent green organic light-emitting diodes exhibit external quantum efficiency >60%, while phosphorescent white organic light-emitting diodes exhibit external quantum efficiency >45% at 10,000 cd m(-2) with colour rendering index of 85. The power efficiency of white organic light-emitting diodes reaches 80 lm W(-1) at 3,000 cd m(-2), comparable to the most efficient lighting technologies.

摘要

有机发光二极管正逐渐成为高质量显示和照明的主要技术。然而,目前有机发光二极管技术中使用的透明导电电极增加了整体成本,并且对于未来的柔性应用具有有限的柔韧性。在这里,我们使用单层石墨烯作为替代柔性透明导体,产生了具有足够亮度和效率的白色有机发光二极管,可用于一般照明。性能的提高归因于器件结构,该结构允许空穴从单层石墨烯阳极直接注入发光层,从而减少了载流子俘获引起的效率下降。通过采用光取出耦合结构,磷光绿色有机发光二极管的外量子效率>60%,而磷光白色有机发光二极管在 10,000 cd m(-2)下的外量子效率>45%,显色指数为 85。白色有机发光二极管的功率效率在 3,000 cd m(-2)时达到 80 lm W(-1),可与最高效的照明技术相媲美。

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