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并苯(a)芘/蒄比值能否作为机动车排放的独特标志物?

Can Coronene and/or Benzo(a)pyrene/Coronene ratio act as unique markers for vehicle emission?

机构信息

Institute of Climate and Global Change Research, School of Atmospheric Sciences, Nanjing University, Nanjing 210093, China; Jiangsu Academy of Environmental Sciences, Nanjing 210036, China; Laboratory of Earth Surface Processes, College of Urban and Environmental Sciences, Peking University, Beijing 100871, China.

出版信息

Environ Pollut. 2014 Jan;184:650-3. doi: 10.1016/j.envpol.2013.08.020. Epub 2013 Sep 15.

DOI:10.1016/j.envpol.2013.08.020
PMID:24048010
Abstract

Coronene is a high molecular weight polycyclic aromatic hydrocarbon with seven aromatic rings. It, more specifically a lower ratio of Benzo[a]pyrene to Coronone (BaP/COR), is suggested as a marker for vehicle emission. In the present study, emissions of Coronene were measured from residential combustions of wood, crop straw, and pellets. The detection of COR in non-vehicle emission sources, and comparable BaP/COR ratios between the solid fuel combustion and vehicle emissions indicated that the generality of COR or the BaP/COR ratio as markers for the vehicle emission would be questionable, especially for the area where solid fuel combustion dominated the PAHs emission.

摘要

蔻烯是一种高分子量的多环芳烃,具有七个芳香环。它,更具体地说,是苯并[a]芘与蔻烯的较低比值(BaP/COR),被认为是车辆排放的标志物。在本研究中,从木材、农作物秸秆和颗粒的住宅燃烧中测量了蔻烯的排放。蔻烯在非车辆排放源中的检测,以及固体燃料燃烧和车辆排放之间可比的 BaP/COR 比值表明,COR 或 BaP/COR 比值作为车辆排放标志物的通用性值得怀疑,特别是在固体燃料燃烧主导多环芳烃排放的地区。

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