金（I）催化的利用烯丙醇和酚一锅法合成色满。
Gold(I)-catalysed one-pot synthesis of chromans using allylic alcohols and phenols.
机构信息
Institute of Chemical Sciences, Heriot-Watt University, Edinburgh, EH14 1LP, United Kingdom.
出版信息
Beilstein J Org Chem. 2013 Sep 4;9:1797-806. doi: 10.3762/bjoc.9.209. eCollection 2013.
Abstract
A gold(I)-catalysed reaction of allylic alcohols and phenols produces chromans regioselectively via a one-pot Friedel-Crafts allylation/intramolecular hydroalkoxylation sequence. The reaction is mild, practical and tolerant of a wide variety of substituents on the phenol.
摘要
金（I）催化的烯丙醇和酚的反应通过一锅 Friedel-Crafts 烯丙基化/分子内烷氧基化反应序列以区域选择性方式生成色满。该反应条件温和、实用，并且对酚上的各种取代基具有良好的耐受性。
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