铑(III)催化的肼导向的 C-H 活化合成吲哚：通过 N-N 键断裂实现氧化还原中性和无痕。
Indole synthesis by rhodium(III)-catalyzed hydrazine-directed C-H activation: redox-neutral and traceless by N-N bond cleavage.
机构信息
Westfälische Wilhelms-Universität Münster, Organisch-Chemisches Institut, Corrensstrasse 40, 48149 Münster (Germany) http://www.uni-muenster.de/Chemie.oc/glorius/index.html.
出版信息
Angew Chem Int Ed Engl. 2013 Nov 18;52(47):12426-9. doi: 10.1002/anie.201306098. Epub 2013 Sep 25.
PMID:24222579
Abstract
Fishing for complements! There is an alternative to the useful Fischer indole synthesis. The new method utilizes the same retrosynthetic disconnection but is based on a Rh(III) -catalyzed directed CH activation step and a successive coupling with alkynes.
摘要
钓补法！除了 Fischer 吲哚合成法，还有另一种有用的方法。该新法利用相同的逆合成切断，但基于 Rh(III)催化的导向 CH 活化步骤和与炔烃的连续偶联。
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