State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, People's Republic of China.
Chem Commun (Camb). 2014 Jan 14;50(4):472-4. doi: 10.1039/c3cc47780k.
A ketal-tether approach for the stereoselective synthesis of [5,5] and [5,6]-spiroketals based on reductive coupling catalyzed by the readily available Ni complex is demonstrated. Either an intermolecular or an intramolecular stereospecific cascade has been achieved as well.
酮缩醇键法用于立体选择性合成[5,5]和[5,6]-螺缩酮，反应由易得的镍配合物催化，通过还原偶联实现。无论是分子间还是分子内的立体特异性级联反应都可以实现。
