Chemical Sciences Division, Lawrence Berkeley National Laboratory, and Department of Chemistry, University of California , Berkeley, California 94720, United States.
J Am Chem Soc. 2013 Dec 18;135(50):18802-5. doi: 10.1021/ja411631v. Epub 2013 Dec 5.
The synthesis of a novel supramolecular tetrahedral assembly of K12Ga4L6 stoichiometry is reported. The newly designed chiral ligand exhibits high diastereoselective control during cluster formation, leading exclusively to a single diastereomer of the desired host. This new assembly also exhibits high stability toward oxidation or a low pH environment and is a more robust and efficient catalyst for asymmetric organic transformations of neutral substrates.
本文报道了一种新型超分子四面体 K12Ga4L6 配合物的合成。新设计的手性配体在形成簇时表现出高的非对映选择性控制，仅得到所需主体的单一非对映异构体。这种新的组装体对氧化或低 pH 环境也表现出高的稳定性，并且是更有效的不对称有机转化的中性底物的催化剂。
