Deng Zhen, Jiang Yang, Ma Ziguang, Wang Wenxin, Jia Haiqiang, Zhou Junming, Chen Hong
Key Laboratory for Renewable Energy, Chinese Academy of Sciences, Beijing 100190, China.
Beijing Key Laboratory for New Energy Materials and Devices, Beijing 100190, China.
Sci Rep. 2013 Dec 17;3:3389. doi: 10.1038/srep03389.
The pursuit of high internal quantum efficiency (IQE) for green emission spectral regime is referred as "green gap" challenge. Now researchers place their hope on the InGaN-based materials to develop high-brightness green light-emitting diodes. However, IQE drops fast when emission wavelength of InGaN LED increases by changing growth temperature or well thickness. In this paper, a new wavelength-adjusting method is proposed and the optical properties of LED are investigated. By additional process of indium pre-deposition before InGaN well layer growth, the indium distribution along growth direction becomes more uniform, which leads to the increase of average indium content in InGaN well layer and results in a redshift of peak-wavelength. We also find that the IQE of LED with indium pre-deposition increases with the wavelength redshift. Such dependence is opposite to the IQE-wavelength behavior in conventional InGaN LEDs. The relations among the IQE, wavelength and the indium pre-deposition process are discussed.
追求绿色发光光谱范围内的高内量子效率(IQE)被称为“绿色差距”挑战。目前,研究人员将希望寄托在基于氮化铟镓(InGaN)的材料上,以开发高亮度绿色发光二极管。然而,当通过改变生长温度或阱层厚度来增加InGaN发光二极管的发射波长时,内量子效率会迅速下降。本文提出了一种新的波长调节方法,并对发光二极管的光学特性进行了研究。通过在InGaN阱层生长之前进行额外的铟预沉积工艺,沿生长方向的铟分布变得更加均匀,这导致InGaN阱层中平均铟含量增加,并使峰值波长发生红移。我们还发现,经过铟预沉积的发光二极管的内量子效率随着波长红移而增加。这种依赖性与传统InGaN发光二极管中内量子效率与波长的关系相反。本文讨论了内量子效率、波长与铟预沉积工艺之间的关系。