Department of Chemistry, Indiana University, Bloomington, Indiana 47405, USA.
Chem Soc Rev. 2014 Jun 7;43(11):3823-34. doi: 10.1039/c3cs60347d. Epub 2013 Dec 19.
The optical properties of metal nanomaterials are determined by a set of parameters that include composition, particle size and shape, overall architecture, and local environment. This Tutorial Review examines the influence of each of these factors on the localized surface plasmon resonance of colloidal metal nanoparticles. This examination is paralleled with a discussion of the advances which have enabled the synthesis of structurally defined metal nanomaterials, as these samples serve as the best platforms for elucidating the fundamental properties of plasmonic colloids. Based on the analysis of such samples, five guidelines are presented to aid the rational design and synthesis of new metal nanostructures for advanced applications in nanomedicine, energy, chemical sensing, and colloidal plasmonics in general.
金属纳米材料的光学性质由一组参数决定，包括组成、颗粒大小和形状、整体结构和局部环境。本教程综述考察了这些因素中的每一个因素对胶体金属纳米粒子局域表面等离子体共振的影响。与此同时，还讨论了使结构明确的金属纳米材料合成成为可能的进展，因为这些样品是阐明等离子体胶体基本性质的最佳平台。基于对这些样品的分析，提出了五条准则，以帮助合理设计和合成用于纳米医学、能源、化学传感和一般胶体等离子体学等先进应用的新型金属纳米结构。
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