Department of Chemistry , University of Minnesota , 207 Pleasant Street Southeast , Minneapolis , Minnesota 55455 , United States.
Chem Rev. 2019 Jan 9;119(1):664-699. doi: 10.1021/acs.chemrev.8b00341. Epub 2018 Oct 22.
Noble metal nanoparticles have been extensively studied to understand and apply their plasmonic responses, upon coupling with electromagnetic radiation, to research areas such as sensing, photocatalysis, electronics, and biomedicine. The plasmonic properties of metal nanoparticles can change significantly with changes in particle size, shape, composition, and arrangement. Thus, stabilization of the fabricated nanoparticles is crucial for preservation of the desired plasmonic behavior. Because plasmonic nanoparticles find application in diverse fields, a variety of different stabilization strategies have been developed. Often, stabilizers also function to enhance or improve the plasmonic properties of the nanoparticles. This review provides a representative overview of how gold and silver nanoparticles, the most frequently used materials in current plasmonic applications, are stabilized in different application platforms and how the stabilizing agents improve their plasmonic properties at the same time. Specifically, this review focuses on the roles and effects of stabilizing agents such as surfactants, silica, biomolecules, polymers, and metal shells in colloidal nanoparticle suspensions. Stability strategies for other types of plasmonic nanomaterials, lithographic plasmonic nanoparticle arrays, are discussed as well.
贵金属纳米粒子已被广泛研究,以了解并应用其在与电磁辐射耦合时的等离子体响应,研究领域包括传感、光催化、电子学和生物医学等。金属纳米粒子的等离子体特性会随着粒子尺寸、形状、组成和排列的变化而发生显著变化。因此,为了保持所需的等离子体行为,对所制造的纳米粒子进行稳定化至关重要。由于等离子体纳米粒子在不同领域都有应用,因此已经开发出了各种不同的稳定化策略。通常,稳定剂还可以增强或改善纳米粒子的等离子体特性。本综述提供了一个代表性的概述,介绍了在不同的应用平台中如何稳定金和银纳米粒子(当前等离子体应用中最常用的材料),以及稳定剂如何同时改善它们的等离子体特性。具体来说,本综述重点介绍了表面活性剂、二氧化硅、生物分子、聚合物和金属壳等稳定剂在胶体纳米粒子悬浮液中的作用和影响。同时还讨论了其他类型的等离子体纳米材料(如光刻等离子体纳米粒子阵列)的稳定化策略。
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