固氮酶固氮的机制：下一阶段 - Suppr

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Mechanism of nitrogen fixation by nitrogenase: the next stage.

作者信息

Hoffman Brian M, Lukoyanov Dmitriy, Yang Zhi-Yong, Dean Dennis R, Seefeldt Lance C

机构信息

Department of Chemistry and Biochemistry, Utah State University , 0300 Old Main Hill, Logan, Utah 84322, United States.

出版信息

Chem Rev. 2014 Apr 23;114(8):4041-62. doi: 10.1021/cr400641x. Epub 2014 Jan 27.

DOI:10.1021/cr400641x

PMID:24467365

原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4012840/

Abstract

摘要

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a094/4012840/cad6d3205753/cr-2013-00641x_0007.jpg

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Nitrogenase: a general hydrogenator of small molecules.

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Mechanistic aspects of dinitrogen cleavage and hydrogenation to produce ammonia in catalysis and organometallic chemistry: relevance of metal hydride bonds and dihydrogen.

Chem Soc Rev. 2014 Jan 21;43(2):547-64. doi: 10.1039/c3cs60206k.

Electron transfer precedes ATP hydrolysis during nitrogenase catalysis.

Proc Natl Acad Sci U S A. 2013 Oct 8;110(41):16414-9. doi: 10.1073/pnas.1311218110. Epub 2013 Sep 23.

On reversible H2 loss upon N2 binding to FeMo-cofactor of nitrogenase.

Proc Natl Acad Sci U S A. 2013 Oct 8;110(41):16327-32. doi: 10.1073/pnas.1315852110. Epub 2013 Sep 23.

Catalytic conversion of nitrogen to ammonia by an iron model complex.

Nature. 2013 Sep 5;501(7465):84-7. doi: 10.1038/nature12435.

Heterolytic H Cleavage and Catalytic Hydrogenation by an Iron Metallaboratrane.

Organometallics. 2013 May 24;32(10):3053-3062. doi: 10.1021/om400281v.

Recent developments in the homogeneous reduction of dinitrogen by molybdenum and iron.

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相似文献

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Chem Rev. 2014 Apr 23;114(8):4041-62. doi: 10.1021/cr400641x. Epub 2014 Jan 27.

Vanadium nitrogenase: a two-hit wonder?

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本文引用的文献

Crystallographic structure and functional implications of the nitrogenase molybdenum-iron protein from azotobacter vinelandii.

Nature. 1992 Dec 10;360(6404):553-60. doi: 10.1038/360553a0.

Nitrogenase: a general hydrogenator of small molecules.

Chem Commun (Camb). 2013 Dec 4;49(93):10893-907. doi: 10.1039/c3cc46864j.

Mechanistic aspects of dinitrogen cleavage and hydrogenation to produce ammonia in catalysis and organometallic chemistry: relevance of metal hydride bonds and dihydrogen.

Chem Soc Rev. 2014 Jan 21;43(2):547-64. doi: 10.1039/c3cs60206k.

Electron transfer precedes ATP hydrolysis during nitrogenase catalysis.

Proc Natl Acad Sci U S A. 2013 Oct 8;110(41):16414-9. doi: 10.1073/pnas.1311218110. Epub 2013 Sep 23.

On reversible H2 loss upon N2 binding to FeMo-cofactor of nitrogenase.

Proc Natl Acad Sci U S A. 2013 Oct 8;110(41):16327-32. doi: 10.1073/pnas.1315852110. Epub 2013 Sep 23.

Catalytic conversion of nitrogen to ammonia by an iron model complex.

Nature. 2013 Sep 5;501(7465):84-7. doi: 10.1038/nature12435.

Heterolytic H Cleavage and Catalytic Hydrogenation by an Iron Metallaboratrane.

Organometallics. 2013 May 24;32(10):3053-3062. doi: 10.1021/om400281v.

Recent developments in the homogeneous reduction of dinitrogen by molybdenum and iron.

Nat Chem. 2013 Jul;5(7):559-65. doi: 10.1038/nchem.1620. Epub 2013 May 26.

Nitrogenase reduction of carbon-containing compounds.

Biochim Biophys Acta. 2013 Aug-Sep;1827(8-9):1102-11. doi: 10.1016/j.bbabio.2013.04.003. Epub 2013 Apr 16.

Biosynthesis of the iron-molybdenum cofactor of nitrogenase.

J Biol Chem. 2013 May 10;288(19):13173-7. doi: 10.1074/jbc.R113.454041. Epub 2013 Mar 28.