CENIMAT/I3N, Departamento de Ciência dos Materiais, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, Campus de Caparica, 2829-516 Caparica, Portugal.
Nanotechnology. 2014 Mar 7;25(9):094008. doi: 10.1088/0957-4484/25/9/094008. Epub 2014 Feb 12.
Cotton-based nanocrystalline cellulose (NCC), also known as nanopaper, one of the major sources of renewable materials, is a promising substrate and component for producing low cost fully recyclable flexible paper electronic devices and systems due to its properties (lightweight, stiffness, non-toxicity, transparency, low thermal expansion, gas impermeability and improved mechanical properties).Here, we have demonstrated for the first time a thin transparent nanopaper-based field effect transistor (FET) where NCC is simultaneously used as the substrate and as the gate dielectric layer in an 'interstrate' structure, since the device is built on both sides of the NCC films; while the active channel layer is based on oxide amorphous semiconductors, the gate electrode is based on a transparent conductive oxide.Such hybrid FETs present excellent operating characteristics such as high channel saturation mobility (>7 cm(2) V (-1) s(-1)), drain-source current on/off modulation ratio higher than 10(5), enhancement n-type operation and subthreshold gate voltage swing of 2.11 V/decade. The NCC film FET characteristics have been measured in air ambient conditions and present good stability, after two weeks of being processed, without any type of encapsulation or passivation layer. The results obtained are comparable to ones produced for conventional cellulose paper, marking this out as a promising approach for attaining high-performance disposable electronics such as paper displays, smart labels, smart packaging, RFID (radio-frequency identification) and point-of-care systems for self-analysis in bioscience applications, among others.
基于棉的纳米纤维素(NCC),也称为纳米纸,是可再生材料的主要来源之一,由于其特性(轻量级、刚性、无毒、透明、低热膨胀、不透气体和改善的机械性能),是生产低成本完全可回收的柔性纸电子设备和系统的有前途的基底和组件。在这里,我们首次展示了一种薄的透明纳米纸基场效应晶体管(FET),其中 NCC 同时用作基底和“层间”结构中的栅介质层,因为该器件构建在 NCC 薄膜的两侧;而有源沟道层基于非晶氧化物半导体,栅电极基于透明导电氧化物。这种混合 FET 具有出色的工作特性,例如高沟道饱和迁移率(>7 cm(2) V(-1) s(-1))、漏源电流开/关调制比高于 10(5)、增强的 n 型操作和亚阈值栅电压摆幅为 2.11 V/decade。在空气环境条件下测量了 NCC 薄膜 FET 的特性,并且在没有任何类型的封装或钝化层的情况下,在经过两周的处理后,仍具有良好的稳定性。所获得的结果与用于常规纤维素纸的结果相当,这标志着这是实现高性能一次性电子产品的有前途的方法,例如纸显示器、智能标签、智能包装、RFID(射频识别)和生物科学应用中的自我分析等点护理系统。