Zhu Huan, Guo Zhiguang, Liu Weimin
Ministry of Education Key Laboratory for the Green Preparation and Application of Functional Materials and Hubei Collaborative Innovation Centre for Advanced Organic Chemical Materials, Hubei University, Wuhan 430062, People's Republic of China.
Chem Commun (Camb). 2014 Apr 18;50(30):3900-13. doi: 10.1039/c3cc47818a. Epub 2014 Feb 27.
The adhesion behaviors of superhydrophobic surfaces have become an emerging topic to researchers in various fields as a vital step in the interactions between materials and organisms/materials. Controlling the chemical compositions and topological structures via various methods or technologies is essential to fabricate and modulate different adhesion properties, such as low-adhesion, high-adhesion and anisotropic adhesion on superhydrophobic surfaces. We summarize the recent developments in both natural superhydrophobic surfaces and artificial superhydrophobic surfaces with various adhesions and also pay attention to superhydrophobic surfaces switching between low- and high-adhesion. The methods to regulate or translate the adhesion of superhydrophobic surfaces can be considered from two perspectives. One is to control the chemical composition and change the surface geometric structure on the surfaces, respectively or simultaneously. The other is to provide external stimulations to induce transitions, which is the most common method for obtaining switchable adhesions. Additionally, adhesion behaviors on solid-solid interfaces, such as the behaviors of cells, bacteria, biomolecules and icing on superhydrophobic surfaces are also noticeable and controversial. This review is aimed at giving a brief and crucial overview of adhesion behaviors on superhydrophobic surfaces.
超疏水表面的粘附行为已成为各个领域研究人员关注的新兴课题,它是材料与生物体/材料相互作用中的关键一步。通过各种方法或技术控制化学成分和拓扑结构对于在超疏水表面制造和调节不同的粘附特性至关重要,例如低粘附、高粘附和各向异性粘附。我们总结了具有各种粘附特性的天然超疏水表面和人工超疏水表面的最新进展,同时也关注超疏水表面在低粘附和高粘附之间的切换。调节或转变超疏水表面粘附力的方法可以从两个角度来考虑。一是分别或同时控制化学成分并改变表面的几何结构。另一种是提供外部刺激以诱导转变,这是获得可切换粘附力最常用的方法。此外,固-固界面上的粘附行为,如细胞、细菌、生物分子在超疏水表面的行为以及结冰现象也值得关注且存在争议。本综述旨在对超疏水表面的粘附行为进行简要而关键的概述。