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基于扩展-π 共轭受体和硫桥环芳烃的电荷转移配合物晶体：电荷转移相互作用和显著的双极性输运特性。

Charge-transfer complex crystal based on extended-π-conjugated acceptor and sulfur-bridged annulene: charge-transfer interaction and remarkable high ambipolar transport characteristics.

机构信息

Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China; University of Chinese Academy of Sciences, Beijing, 100049, P. R. China.

出版信息

Adv Mater. 2014 Jun 25;26(24):4093-9. doi: 10.1002/adma.201400056. Epub 2014 Mar 24.

DOI:10.1002/adma.201400056
PMID:24664869
Abstract

A single crystal of a novel mixed-stack donor-acceptor complex formed by a tetracyanoquinodimethane derivative with an extended π-conjugated system and a sulfur-bridged annulene displays the highest ambipolar transport behavior among donor-acceptor complexes reported with electron and hole mobilities reaching up to 0.24 and 0.77 cm(2) V(-1) s(-1) , respectively.

摘要

一种新型的混合堆积给体-受体络合物的单晶由一个具有扩展的π共轭体系的四氰基对醌二甲烷衍生物和一个硫桥联的并环芳烃形成，在报道的给体-受体络合物中表现出最高的双极性输运性能，电子和空穴迁移率分别高达 0.24 和 0.77 cm(2) V(-1) s(-1) 。

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