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Radical arylalkoxycarbonylation of 2-isocyanobiphenyl with carbazates: dual C-C bond formation toward phenanthridine-6-carboxylates.

作者信息

Pan Changduo, Han Jie, Zhang Honglin, Zhu Chengjian

机构信息

State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University , Nanjing 210093, P. R. China.

出版信息

J Org Chem. 2014 Jun 6;79(11):5374-8. doi: 10.1021/jo500842e. Epub 2014 May 13.

Abstract

A sequential oxidative radical alkoxycarbonylation and aromatization of 2-isocyanobiphenyl with carbazates was developed to furnish phenanthridine-6-carboxylates. Various functional groups such as methoxy, chloro, fluoro, trifluoromethoxy, and trifluoromethyl groups were tolerated well under the reaction conditions. The sequential radical addition-cyclization strategy represents a practical route to access phenanthridine-6-carboxylates.

摘要

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