铁（III）-萨伦配合物催化β-酮酯和N-叔丁氧羰基氧化吲哚的高度对映选择性氟化和羟基化反应。
Iron(III)-salan complexes catalysed highly enantioselective fluorination and hydroxylation of β-keto esters and N-Boc oxindoles.
作者信息
Gu Xin, Zhang Yan, Xu Zhen-Jiang, Che Chi-Ming
机构信息
Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, 354 Feng Lin Road, Shanghai, China.
出版信息
Chem Commun (Camb). 2014 Jul 25;50(58):7870-3. doi: 10.1039/c4cc01631a.
PMID:24910967
Abstract
Chiral iron(iii)-salan complexes catalysed highly enantioselective α-fluorination and α-hydroxylation of β-keto esters and N-Boc oxindoles to give the corresponding products in high yields and good-to-excellent ee values under mild reaction conditions.
摘要
手性铁（III）-salan配合物催化β-酮酯和N-Boc氧化吲哚的高度对映选择性α-氟化和α-羟基化反应，在温和的反应条件下以高收率和良好至优异的对映体过量值得到相应产物。
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