亚烷基环丙烷和亚烷基环丁烷的合成与转化研究进展 - Suppr

Progress in the synthesis and transformations of alkylidenecyclopropanes and alkylidenecyclobutanes.

作者信息

Brandi Alberto, Cicchi Stefano, Cordero Franca M, Goti Andrea

机构信息

Dipartimento di Chimica "Ugo Schiff", Università degli Studi di Firenze , Via della Lastruccia 13, I-50019-Sesto Fiorentino, Italy.

出版信息

Chem Rev. 2014 Aug 13;114(15):7317-420. doi: 10.1021/cr400686j. Epub 2014 Jun 13.

DOI:10.1021/cr400686j

PMID:24927495

Abstract

摘要

相似文献

Progress in the synthesis and transformations of alkylidenecyclopropanes and alkylidenecyclobutanes.亚烷基环丙烷和亚烷基环丁烷的合成与转化研究进展

Chem Rev. 2014 Aug 13;114(15):7317-420. doi: 10.1021/cr400686j. Epub 2014 Jun 13.

Highly Diastereoselective Strain-Increase Allylborations: Rapid Access to Alkylidenecyclopropanes and Alkylidenecyclobutanes.高非对映选择性应变增加烯丙基硼化反应：快速获得亚烷基环丙烷和亚烷基环丁烷。

J Am Chem Soc. 2021 May 19;143(19):7462-7470. doi: 10.1021/jacs.1c01966. Epub 2021 May 5.

Fluorination of alkylidenecyclopropanes and alkylidenecyclobutanes: divergent synthesis of fluorinated cyclopropanes and cyclobutanes.氟烷基烯丙基环丙烷和烯丙基环丁烷的氟化：氟化环丙烷和环丁烷的不同合成方法。

Org Biomol Chem. 2023 Jul 5;21(26):5356-5360. doi: 10.1039/d3ob00785e.

Synthesis of alkylidenecyclopropanes by palladium-catalyzed reaction of propargyl-substituted malonate esters with aryl halides by anti-carbopalladation pathway.钯催化炔丙基取代丙二酸盐酯与芳基卤化物的反碳钯化途径反应合成亚烷基环丙烷。

J Am Chem Soc. 2011 Jun 29;133(25):9682-5. doi: 10.1021/ja203062z. Epub 2011 Jun 6.

Cu(I)-catalyzed intramolecular C-C coupling of activated methylene compounds with vinyl halides: efficient synthesis of functionalized alkylidenecyclobutanes.铜（I）催化的活性亚甲基化合物与卤代乙烯的分子内碳-碳偶联反应：功能化亚烷基环丁烷的高效合成

Org Lett. 2008 Nov 20;10(22):5285-8. doi: 10.1021/ol802012q. Epub 2008 Oct 16.

Rhodium(I)-catalyzed cycloisomerization of nitrogen-tethered indoles and alkylidenecyclopropanes: convenient access to polycyclic indole derivatives.铑（I）催化的氮桥联吲哚和亚甲基环丙烷的环异构化反应：多环吲哚衍生物的便捷合成方法。

Chemistry. 2013 Oct 4;19(41):13668-73. doi: 10.1002/chem.201302331. Epub 2013 Sep 17.

Highly regio- and stereoselective synthesis of alkylidenecyclopropanes via Ru(II)-Pheox catalyzed asymmetric inter- and intramolecular cyclopropanation of allenes.通过 Ru(II)-Pheox 催化的丙二烯的不对称分子内和分子间环丙烷化反应，高区域和立体选择性合成亚烷基环丙烷。

Org Lett. 2014 Jun 20;16(12):3408-11. doi: 10.1021/ol5014944. Epub 2014 Jun 11.

Iodohydroxylation of alkylidenecyclopropanes. An efficient synthesis of iodocyclopropylmethanol and 3-iodobut-3-en-1-ol derivatives.

J Org Chem. 2008 Jun 20;73(12):4702-4. doi: 10.1021/jo800123m. Epub 2008 May 24.

Acylation of alkylidenecyclopropanes for the facile synthesis of alpha,beta-unsaturated ketone and benzofulvene derivatives with high stereoselectivity.

Org Lett. 2007 Apr 26;9(9):1667-70. doi: 10.1021/ol070331h. Epub 2007 Mar 27.

Synthesis of 5-azaindolizine derivatives by the palladium-catalyzed intermolecular formal [3+2] cycloaddition of alkylidenecyclopropanes with 1,2-diazines.通过钯催化亚烷基环丙烷与1,2 - 二嗪的分子间形式[3 + 2]环加成反应合成5 - 氮杂吲哚嗪衍生物

J Org Chem. 2004 Apr 30;69(9):3202-4. doi: 10.1021/jo035810i.

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Catalytic enantioselective synthesis of alkylidenecyclopropanes.亚烷基环丙烷的催化对映选择性合成

Nature. 2025 Aug 11. doi: 10.1038/s41586-025-09485-y.

Cu-Catalyzed Chemoselective Borylcupration of Borylated ()‑Skipped Dienoates: A Case Study for the Synthesis of -diborylcyclobutanes.铜催化硼化（）-跳跃二烯酸酯的化学选择性硼铜化反应：合成 - 二硼基环丁烷的实例研究

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[2,3]-Sigmatropic rearrangement with [1.1.1]propellane.[2,3] - 迁移重排反应与[1.1.1] - 螺桨烷

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Skeletal Modification via Activation of Relatively Unstrained C-C Bonds.通过激活相对无张力的碳-碳键实现骨架修饰。

Acc Chem Res. 2025 Mar 18;58(6):991-1002. doi: 10.1021/acs.accounts.5c00014. Epub 2025 Mar 6.

Cobalt-Catalyzed (3 + 2) Cycloaddition of Cyclopropene-Tethered Alkynes: Versatile Access to Bicyclic Cyclopentadienyl Systems and Their CpM Complexes.钴催化环丙烯连接的炔烃的(3 + 2)环加成反应：构建双环环戊二烯基体系及其CpM配合物的通用方法

ACS Catal. 2024 Jul 20;14(15):11574-11583. doi: 10.1021/acscatal.4c03080. eCollection 2024 Aug 2.

A highly diastereoselective strain-release Doyle-Kirmse reaction: access to functionalized difluoro(methylene)cyclopropanes.一种高度非对映选择性的应变释放多伊尔-基尔姆塞反应：通往官能化二氟（亚甲基）环丙烷的途径。

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Cobalt(I)-Catalyzed (3 + 2 + 2) Cycloaddition between Alkylidenecyclopropanes, Alkynes, and Alkenes.钴（I）催化的亚烷基环丙烷、炔烃和烯烃之间的（3 + 2 + 2）环加成反应

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A general catalytic synthetic strategy for highly strained methylenecyclobutanes and spiromethylenecyclobutanes.一种用于高张力亚甲基环丁烷和螺亚甲基环丁烷的通用催化合成策略。

Chem Sci. 2023 Jun 9;14(29):7897-7904. doi: 10.1039/d3sc01103h. eCollection 2023 Jul 26.

Cobalt-catalyzed radical-mediated carbon-carbon scission a radical-type migratory insertion.钴催化的自由基介导的碳-碳断裂——一种自由基型迁移插入反应。

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Palladium- and Brønsted acid-catalyzed enantio-, site- and /-selective addition of alkylidenecyclopropanes with imines.钯和布朗斯特酸催化的亚烷基环丙烷与亚胺的对映、位点和 / -选择性加成反应。

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Progress in the synthesis and transformations of alkylidenecyclopropanes and alkylidenecyclobutanes.

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