通过光催化实现烷基碳氢键的选择性氟化。
Selective fluorination of alkyl C-H bonds via photocatalysis.
作者信息
Kee Choon Wee, Chin Kek Foo, Wong Ming Wah, Tan Choon-Hong
机构信息
School of Physical & Mathematical Sciences, Division of Chemistry and Biological Chemistry, Nanyang Technological University, 21 Nanyang Link, Singapore 637371, Singapore.
出版信息
Chem Commun (Camb). 2014 Aug 4;50(60):8211-4. doi: 10.1039/c4cc01848f.
PMID:24930896
Abstract
We report the generation of cationic N-radicals from Selectfluor® via energy transfer with anthraquinone as a photocatalyst for the fluorination of unactivated C-H bonds.
摘要
我们报道了通过与蒽醌作为光催化剂进行能量转移，从Selectfluor®生成阳离子N-自由基，用于未活化C-H键的氟化反应。
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