Trotta Francesco, Biasizzo Miriam, Caldera Fabrizio
Department of Chemistry, University of Torino, Via Pietro Giuria 7, 10125 Torino, Italy.
Membranes (Basel). 2012 Jul 19;2(3):440-77. doi: 10.3390/membranes2030440.
Although the roots of molecularly imprinted polymers lie in the beginning of 1930s in the past century, they have had an exponential growth only 40-50 years later by the works of Wulff and especially by Mosbach. More recently, it was also proved that molecular imprinted membranes (i.e., polymer thin films) that show recognition properties at molecular level of the template molecule are used in their formation. Different procedures and potential application in separation processes and catalysis are reported. The influences of different parameters on the discrimination abilities are also discussed.
尽管分子印迹聚合物的根源可追溯到上世纪20世纪30年代初，但直到40 - 50年后，在伍尔夫尤其是莫斯巴赫的研究成果推动下，它们才呈指数级增长。最近还证明，在模板分子的分子水平上具有识别特性的分子印迹膜（即聚合物薄膜）被用于其形成过程。文中报道了不同的制备方法以及在分离过程和催化方面的潜在应用。还讨论了不同参数对识别能力的影响。
