Stratingh Institute for Chemistry, University of Groningen , Nijenborgh 4, 9747 AG Groningen, The Netherlands.
J Am Chem Soc. 2014 Jul 16;136(28):9894-7. doi: 10.1021/ja505281v. Epub 2014 Jun 30.
Copper-catalysis allows the direct oxygen-arylation of dialkyl phosphonates with diaryliodonium salts. This novel methodology proceeds with a wide range of phosphonates and phosphoramidates under mild conditions and gives straightforward access to valuable mixed alkyl aryl phosphonates in very good yields and near perfect selectivity.
铜催化实现了二烷基膦酸酯与二芳基碘鎓盐的直接氧芳基化反应。该新方法在温和条件下适用于多种膦酸酯和磷酰胺，以非常好的收率和近乎完美的选择性，直接得到有价值的混合烷基芳基膦酸酯。
