连续的异氰化物基多组分反应：环状五肽的合成。
Consecutive isocyanide-based multicomponent reactions: synthesis of cyclic pentadepsipeptoids.
机构信息
Laboratório de Química Metodológica e Orgânica Sintética, Instituto de Química, Universidade de Brasília, CP 4478, 70910-970 Brasília-DF, Brazil.
Faculdade UnB Planaltina, Área Universitária Nº 1, Vila Nossa Senhora de Fátima, Planaltina, 73300-000, Brasília, DF, Brazil.
出版信息
Beilstein J Org Chem. 2014 May 5;10:1017-22. doi: 10.3762/bjoc.10.101. eCollection 2014.
The synthesis of six cyclic depsipeptoids inspired by the natural depsipeptide sansalvamide A is described. An efficient and fast synthetic strategy was developed using a combination of consecutive isocyanide-based multicomponent reactions (Ugi and Passerini reactions). This methodology can be used to access a variety of cyclic oligodepsipeptoids.
描述了受天然环肽 sansalvamide A 启发的六种环二肽的合成。通过连续的基于异氰化物的多组分反应（Ugi 和 Passerini 反应）的组合，开发了一种高效且快速的合成策略。该方法可用于获得各种环状寡二肽。
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