Carboni Aude, Dagousset Guillaume, Magnier Emmanuel, Masson Géraldine
Centre de Recherche de Gif, Institut de Chimie des Substances Naturelles, CNRS, 91198 Gif-sur-Yvette Cedex, France.
Chem Commun (Camb). 2014 Nov 25;50(91):14197-200. doi: 10.1039/c4cc07066f.
We report herein the first photoredox-catalyzed intermolecular aryl- and heteroaryltrifluoromethylation of alkenes. Under the optimized conditions using Umemoto's reagent as a CF3 source, a wide range of styrenes can be readily difunctionalized, affording the corresponding trifluoromethylated adducts in up to 99% yield.
我们在此报告首例光氧化还原催化的烯烃分子间芳基和杂芳基三氟甲基化反应。在使用梅本试剂作为CF3源的优化条件下，多种苯乙烯能够轻松实现双官能化，以高达99%的产率得到相应的三氟甲基化加合物。
