Laboratory for Atomistic and Molecular Mechanics (LAMM), Department of Civil and Environmental Engineering, Massachusetts Institute of Technology , 77 Massachusetts Avenue, Room 1-239, Cambridge, Massachusetts 02139, United States.
Nano Lett. 2014 Nov 12;14(11):6520-5. doi: 10.1021/nl503097u. Epub 2014 Oct 24.
Graphene has attracted intense attention to the use in extreme applications. However, its small thickness facilitates wrinkle formation, and it is not clear how such structural change affects its area-specific capacitance. Herein, we combine molecular dynamics and continuum mechanics-based simulations to study the changes in surface area induced by wrinkles. We find that the high specific surface area of graphene can only be affected up to 2% regardless of loading conditions, geometry, and defects.
石墨烯在极端应用中引起了强烈的关注。然而,其较小的厚度容易导致褶皱的形成,目前尚不清楚这种结构变化如何影响其比表面积电容。在此,我们结合分子动力学和基于连续介质力学的模拟来研究褶皱引起的表面积变化。我们发现,无论加载条件、几何形状和缺陷如何,石墨烯的高比表面积只能受到高达 2%的影响。