Wei Yujie, Yang Ronggui
The State Key Laboratory of Nonlinear Mechanics (LNM), Institute of Mechanics, Chinese Academy of Sciences, Beijing 100190, China.
School of Engineering Sciences, University of Chinese Academy of Sciences, Beijing 100049, China.
Natl Sci Rev. 2019 Mar;6(2):324-348. doi: 10.1093/nsr/nwy067. Epub 2018 Jun 19.
The super-high strength of single-layer graphene has attracted great interest. In practice, defects resulting from thermodynamics or introduced by fabrication, naturally or artificially, play a pivotal role in the mechanical behaviors of graphene. More importantly, high strength is just one aspect of the magnificent mechanical properties of graphene: its atomic-thin geometry not only leads to ultra-low bending rigidity, but also brings in many other unique properties of graphene in terms of mechanics in contrast to other carbon allotropes, including fullerenes and carbon nanotubes. The out-of-plane deformation is of a 'soft' nature, which gives rise to rich morphology and is crucial for morphology control. In this review article, we aim to summarize current theoretical advances in describing the mechanics of defects in graphene and the theory to capture the out-of-plane deformation. The structure-mechanical property relationship in graphene, in terms of its elasticity, strength, bending and wrinkling, with or without the influence of imperfections, is presented.
单层石墨烯的超高强度引起了人们极大的兴趣。实际上,由热力学产生的或通过自然或人工制造引入的缺陷在石墨烯的力学行为中起着关键作用。更重要的是,高强度只是石墨烯卓越力学性能的一个方面:其原子级薄的几何结构不仅导致超低的弯曲刚度,而且与包括富勒烯和碳纳米管在内的其他碳同素异形体相比,在力学方面还赋予了石墨烯许多其他独特性能。面外变形具有“柔软”的性质,这会产生丰富的形态,并且对于形态控制至关重要。在这篇综述文章中,我们旨在总结目前在描述石墨烯中缺陷力学以及捕捉面外变形理论方面的理论进展。介绍了石墨烯在有无缺陷影响下,在弹性、强度、弯曲和褶皱方面的结构 - 力学性能关系。