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储存时间和温度对聚对苯二甲酸乙二醇酯(PET)中锑和一些微量元素释放到瓶装饮用水中影响。

Effects of storage time and temperature on the antimony and some trace element release from polyethylene terephthalate (PET) into the bottled drinking water.

机构信息

Department of Food Hygiene and Control, Faculty of Veterinary Medicine, Tehran University, Tehran, Iran.

Department of Environmental Health Engineering, School of Public Health, Tehran University of Medical Sciences, Tehran, Iran.

出版信息

J Environ Health Sci Eng. 2014 Nov 13;12(1):133. doi: 10.1186/s40201-014-0133-3. eCollection 2014.

Abstract

BACKGROUND AND OBJECTIVES

Heavy metals are considered as one of the major contaminants that can enter into the bottled waters. Antimony (Sb) is a contaminant, which may leach from the polyethylene terephthalate (PET) bottles into the water. The aim of this study was to investigate the content of antimony and other trace elements in bottled waters which was kept in varied storage conditions and temperatures.

MATERIALS AND METHODS

Five time-temperature treatments were carried out on five different brands of commercially available bottled waters. Heavy metal measurement was performed by Inductively Coupled Plasma-Atomic Emission Spectroscopy (ICP-AES) method. Analysis of the collected data was processed by SPSS software.

RESULTS

Antimony concentration was the main concern in our study. The concentrations increased in each of the sample during storage period at all temperatures. The results for different conditions were as follow: at 40°C, in outdoor and at room temperature the Sb concentrations were below the MCLs, i e. 6 ppb. However, at 65°C and 80°C for longer storage times Sb concentration exceeded the MCLs, and variations between the samples were significant (p ≤ 0.05). Storage time and temperature effects on the content of some other trace elements such as Al, Fe were also significant (p ≤ 0.05).

CONCLUSION

By increasing the duration of storage time and temperatures, antimony leaching from the PET bottles into the bottled water increased. The concentration of Al demonstrated an increase in higher temperatures and storage duration, whereas the content of Fe demonstrated no significant differences.

摘要

背景与目的

重金属被认为是可能进入瓶装水中的主要污染物之一。锑(Sb)是一种污染物,可能会从聚对苯二甲酸乙二醇酯(PET)瓶中浸出到水中。本研究旨在调查在不同储存条件和温度下保存的瓶装水中锑和其他微量元素的含量。

材料与方法

对五种市售瓶装水的五个不同品牌进行了五次时-温处理。采用电感耦合等离子体-原子发射光谱法(ICP-AES)测定重金属含量。收集的数据通过 SPSS 软件进行分析。

结果

在我们的研究中,锑浓度是主要关注点。在所有温度下的储存期间,每个样品中的浓度都增加了。不同条件下的结果如下:在 40°C、户外和室温下,Sb 浓度低于 MCLs,即 6 ppb。然而,在 65°C 和 80°C 下储存时间较长时,Sb 浓度超过了 MCLs,并且样品之间的差异具有统计学意义(p≤0.05)。储存时间和温度对其他一些微量元素如 Al、Fe 的含量也有显著影响(p≤0.05)。

结论

随着储存时间和温度的延长,锑从 PET 瓶中浸出到瓶装水中的量增加。在较高的温度和储存时间下,Al 的浓度增加,而 Fe 的含量则没有显著差异。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a45e/4245802/72d13fb823e7/40201_2014_133_Fig1_HTML.jpg

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