Ishida Naoki, Ishikawa Norikazu, Sawano Shota, Masuda Yusuke, Murakami Masahiro
Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto 615-8510, Japan.
Chem Commun (Camb). 2015 Feb 4;51(10):1882-5. doi: 10.1039/c4cc09327e.
Tetralins (tetrahydronaphthalenes) are synthesised from benzocyclobutenols based on the rhodium-catalysed site-selective ring opening followed by intermolecular/intramolecular conjugate addition of the resulting arylrhodium species to electron-deficient alkenes. The produced structures make a remarkable contrast with those available from the same compounds under thermal reaction conditions.
四氢萘是由苯并环丁烯醇合成的，其合成过程基于铑催化的位点选择性开环，随后所得芳基铑物种与缺电子烯烃进行分子间/分子内共轭加成。所生成的结构与在热反应条件下由相同化合物得到的结构形成了显著对比。
