Schneider Bennett W, Lal Niraj N, Baker-Finch Simeon, White Thomas P
Opt Express. 2014 Oct 20;22 Suppl 6:A1422-30. doi: 10.1364/OE.22.0A1422.
Perovskite-on-silicon tandem solar cells show potential to reach > 30% conversion efficiency, but require careful optical control. We introduce here an effective light-management scheme based on the established pyramidal texturing of crystalline silicon cells. Calculations show that conformal deposition of a thin film perovskite solar cell directly onto the textured front surface of a high efficiency silicon cell can yield front surface reflection losses as low as 0.52mA/cm(2). Combining this with a wavelength-selective intermediate reflector between the cells additionally provides effective light-trapping in the high-bandgap top cell, resulting in calculated absolute efficiency gains of 2 - 4%. This approach provides a practical and effective method to adapt existing high efficiency silicon cell designs for use in tandem cells, with conversion efficiencies approaching 35%.
硅基钙钛矿串联太阳能电池有潜力实现超过30%的转换效率,但需要精细的光学控制。我们在此引入一种基于成熟的晶体硅电池金字塔纹理的有效光管理方案。计算表明,将薄膜钙钛矿太阳能电池直接保形沉积在高效硅电池的纹理化前表面上,可使前表面反射损失低至0.52mA/cm²。将此与电池之间的波长选择性中间反射器相结合,还能在高带隙顶部电池中实现有效的光捕获,计算得出绝对效率增益为2% - 4%。这种方法提供了一种实用且有效的方式,可使现有的高效硅电池设计适用于串联电池,转换效率接近35%。