Department of Chemistry, Tsinghua University, Beijing, 100084, P. R. China.
Chem Soc Rev. 2015 Aug 21;44(16):5778-92. doi: 10.1039/c4cs00363b.
The application of the twelve principles of green chemistry in nanoparticle synthesis is a relatively new emerging issue concerning the sustainability. This field has received great attention in recent years due to its capability to design alternative, safer, energy efficient, and less toxic routes towards synthesis. These routes have been associated with the rational utilization of various substances in the nanoparticle preparations and synthetic methods, which have been broadly discussed in this tutorial review. This article is not meant to provide an exhaustive overview of green synthesis of nanoparticles, but to present several pivotal aspects of synthesis with environmental concerns, involving the selection and evaluation of nontoxic capping and reducing agents, the choice of innocuous solvents and the development of energy-efficient synthetic methods.
十二项绿色化学原则在纳米粒子合成中的应用是一个相对较新的可持续发展问题。近年来，由于能够设计替代的、更安全、更节能和毒性更小的合成途径，该领域受到了极大的关注。这些途径与在纳米粒子制备和合成方法中合理利用各种物质有关，在本综述教程中进行了广泛讨论。本文并不是要对纳米粒子的绿色合成进行详尽的概述，而是要介绍一些与环境问题有关的合成的关键方面，涉及无毒稳定剂和还原剂的选择和评估、无害溶剂的选择以及节能合成方法的开发。
