源自碳水化合物的骨架多样性：利用甘露糖进行多羟基化合物的多样性导向合成。
Skeletal diversity from carbohydrates: use of mannose for the diversity-oriented synthesis of polyhydroxylated compounds.
作者信息
Lenci Elena, Menchi Gloria, Guarna Antonio, Trabocchi Andrea
机构信息
Department of Chemistry "Ugo Schiff", University of Florence , via della Lastruccia 13, I-50019 Sesto Fiorentino, Florence, Italy.
出版信息
J Org Chem. 2015 Feb 20;80(4):2182-91. doi: 10.1021/jo502701c. Epub 2015 Feb 11.
PMID:25636147
Abstract
The application of d-mannose as a multipurpose building block from the chiral pool enabled the diversity-oriented synthesis of an array of cyclic and bicyclic scaffolds with polyhydroxylated appendages with the aim to expand the skeletal diversity in the panorama of glycopeptidomimetic compounds.
摘要
将D-甘露糖作为手性源中的多功能结构单元加以应用，能够实现一系列带有多羟基附属基团的环状和双环支架的多样性导向合成，目的是在糖肽模拟物化合物的全景中扩展骨架多样性。
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