†Shanghai Advanced Research Institute, Chinese Academy of Sciences, 99 Haike Road, Shanghai 201210, China.
‡CAS Key Laboratory of Synthetic Chemistry of Natural Substances, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China.
Org Lett. 2015 Apr 17;17(8):1942-5. doi: 10.1021/acs.orglett.5b00654. Epub 2015 Apr 9.
Aryl fluorosulfates were prepared by a simple method and employed as coupling partners in the Suzuki-Miyaura reaction. The cross-coupling reactions were performed in water under air at room temperature without ligands or additives such as surfactants or phase-transfer reagents and proceeded smoothly to give excellent yields. Aryl fluorosulfates could also be used as alternatives to halides or triflates in other coupling reactions.
芳基氟硫酸酯通过一种简单的方法制备，并作为 Suzuki-Miyaura 反应的偶联伙伴使用。在空气存在下，在室温下的水中进行交叉偶联反应，无需使用表面活性剂或相转移试剂等配体或添加剂，反应顺利进行，产率优异。芳基氟硫酸酯也可以替代其他偶联反应中的卤化物或三氟甲磺酸酯。
