Dodson C A, Wedge C J, Murakami M, Maeda K, Wallace M I, Hore P J
Department of Chemistry, University of Oxford, Chemistry Research Laboratory, 12 Mansfield Road, Oxford OX1 3TA, UK.
Chem Commun (Camb). 2015 May 11;51(38):8023-6. doi: 10.1039/c5cc01099c. Epub 2015 Apr 13.
We show that the effects of applied magnetic fields on radical pair reactions can be sensitively measured from sample volumes as low as ∼100 femtolitres using total internal reflection fluorescence microscopy. Development of a fluorescence-based microscope method is likely to be a key step in further miniaturisation that will allow detection of magnetic field effects on single molecules.
我们表明,使用全内反射荧光显微镜,可从低至约100飞升至的样品体积中灵敏地测量外加磁场对自由基对反应的影响。基于荧光的显微镜方法的开发可能是进一步小型化的关键一步,这将允许检测磁场对单分子的影响。