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基于微电机的能量产生。

Micromotor-based energy generation.

机构信息

Department of Nanoengineering, University of California, San Diego, La Jolla, CA 92093 (USA).

出版信息

Angew Chem Int Ed Engl. 2015 Jun 1;54(23):6896-9. doi: 10.1002/anie.201501971. Epub 2015 Apr 23.

Abstract

A micromotor-based strategy for energy generation, utilizing the conversion of liquid-phase hydrogen to usable hydrogen gas (H2), is described. The new motion-based H2-generation concept relies on the movement of Pt-black/Ti Janus microparticle motors in a solution of sodium borohydride (NaBH4) fuel. This is the first report of using NaBH4 for powering micromotors. The autonomous motion of these catalytic micromotors, as well as their bubble generation, leads to enhanced mixing and transport of NaBH4 towards the Pt-black catalytic surface (compared to static microparticles or films), and hence to a substantially faster rate of H2 production. The practical utility of these micromotors is illustrated by powering a hydrogen-oxygen fuel cell car by an on-board motion-based hydrogen and oxygen generation. The new micromotor approach paves the way for the development of efficient on-site energy generation for powering external devices or meeting growing demands on the energy grid.

摘要

一种基于微电机的能量产生策略,利用将液相氢转化为可用氢气(H2),被描述出来。这种基于运动的新型 H2 产生概念依赖于 Pt 黑/Ti 詹纳斯微颗粒马达在硼氢化钠(NaBH4)燃料溶液中的运动。这是首次报道使用 NaBH4 为微马达提供动力。这些催化微马达的自主运动以及气泡的产生导致 NaBH4 向 Pt 黑催化表面的增强混合和传输(与静态微颗粒或薄膜相比),从而导致 H2 产生的速度大大加快。这些微马达的实际应用通过在车载运动式氢气和氧气产生的情况下为氢-氧燃料电池汽车提供动力来说明。这种新的微马达方法为开发高效的现场能源产生铺平了道路,以满足外部设备的动力需求或满足能源网日益增长的需求。

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