López Luis A, López Enol
Instituto Universitario de Química Organometálica "Enrique Moles" and Departamento de Química Orgánica e Inorgánica, Universidad de Oviedo, c/Julián Clavería, 8, 33006-Oviedo, Spain.
Dalton Trans. 2015 Jun 14;44(22):10128-35. doi: 10.1039/c5dt01373a.
Transition metal-catalyzed C-H bond functionalizations of ferrocene derivatives have emerged in the last few years as a versatile tool in synthetic organometallic chemistry. These protocols offer significant advantages over more traditional approaches for the synthesis of functionalized ferrocene derivatives in terms of both atom- and step-economy. In this Perspective, we aim to showcase the state of the art in this field, with special emphasis on recent asymmetric methodologies.
在过去几年中,过渡金属催化的二茂铁衍生物的C-H键官能化反应已成为有机金属合成化学中的一种通用工具。与合成官能化二茂铁衍生物的更传统方法相比,这些方法在原子经济性和步骤经济性方面都具有显著优势。在这篇展望文章中,我们旨在展示该领域的最新进展,特别强调近期的不对称方法。