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采用电子束感生电流显微镜和阴极荧光成像技术对核壳结构 InGaN/GaN 纳米线发光二极管进行分析。

Core-shell InGaN/GaN nanowire light emitting diodes analyzed by electron beam induced current microscopy and cathodoluminescence mapping.

机构信息

Institut d'Electronique Fondamentale, UMR 8622 CNRS, University Paris Sud, 91405 Orsay cedex, France.

出版信息

Nanoscale. 2015 Jul 21;7(27):11692-701. doi: 10.1039/c5nr00623f. Epub 2015 Jun 23.

Abstract

We report on the electron beam induced current (EBIC) microscopy and cathodoluminescence (CL) characterization correlated with compositional analysis of light emitting diodes based on core/shell InGaN/GaN nanowire arrays. The EBIC mapping of cleaved fully operational devices allows to probe the electrical properties of the active region with a nanoscale resolution. In particular, the electrical activity of the p-n junction on the m-planes and on the semi-polar planes of individual nanowires is assessed in top view and cross-sectional geometries. The EBIC maps combined with CL characterization demonstrate the impact of the compositional gradients along the wire axis on the electrical and optical signals: the reduction of the EBIC signal toward the nanowire top is accompanied by an increase of the CL intensity. This effect is interpreted as a consequence of the In and Al gradients in the quantum well and in the electron blocking layer, which influence the carrier extraction efficiency. The interface between the nanowire core and the radially grown layer is shown to produce in some cases a transitory EBIC signal. This observation is explained by the presence of charged traps at this interface, which can be saturated by electron irradiation.

摘要

我们报告了基于核壳 InGaN/GaN 纳米线阵列的发光二极管的电子束感生电流 (EBIC) 显微镜和与成分分析相关的阴极发光 (CL) 特性。完全工作器件的切割 EBIC 映射允许以纳米级分辨率探测活性区的电特性。特别是,评估了各个纳米线的 m 平面和半极性平面上 p-n 结在顶视图和横截面几何形状中的电活性。EBIC 图谱与 CL 特性相结合,证明了沿线材轴的成分梯度对电和光学信号的影响:EBIC 信号朝向纳米线顶部的减少伴随着 CL 强度的增加。这种效应被解释为量子阱和电子阻挡层中 In 和 Al 梯度的结果,这会影响载流子提取效率。证明了纳米线芯和径向生长层之间的界面在某些情况下会产生瞬时 EBIC 信号。这种观察结果可以通过界面处存在带电陷阱来解释,这些陷阱可以通过电子辐照来饱和。

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