一种新设计的用于酯催化氢化的含肼基钌配合物。
A new designed hydrazine group-containing ruthenium complex used for catalytic hydrogenation of esters.
作者信息
Tan Xuefeng, Wang Qingli, Liu Yuanhua, Wang Fangyuan, Lv Hui, Zhang Xumu
机构信息
Key Laboratory of Biomedical Polymers of Ministry of Education & College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, Hubei 430072, China.
出版信息
Chem Commun (Camb). 2015 Aug 7;51(61):12193-6. doi: 10.1039/c5cc04242a.
PMID:26132736
Abstract
A hydrazine group-containing nitrogen-phosphine ligand and corresponding ruthenium complexes were synthesized. When these complexes were used for hydrogenation of esters, excellent performance was observed (TON up to 17, 200). A wide substrate scope was suitable for this catalytic system.
摘要
合成了一种含肼基的氮膦配体及相应的钌配合物。当这些配合物用于酯的氢化反应时，观察到了优异的性能（TON高达17200）。该催化体系适用于广泛的底物范围。
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