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锂离子电池本质上安全吗?

Are Lithium Ion Cells Intrinsically Safe?

作者信息

Dubaniewicz Thomas H, DuCarme Joseph P

机构信息

Office of Mine Safety and Health Research, National Institute for Occupational Safety and Health, Pittsburgh, PA 15236, USA.

出版信息

IEEE Trans Ind Appl. 2013 Nov;49(6):2451-2460. doi: 10.1109/TIA.2013.2263274.

Abstract

National Institute for Occupational Safety and Health researchers are studying the potential for Li-ion-battery thermal runaway from an internal short circuit in equipment approved as permissible for use in underground coal mines. Researchers used a plastic wedge to induce internal short circuits for thermal runaway susceptibility evaluation purposes, which proved to be a more severe test than the flat plate method for selected Li-ion cells. Researchers conducted cell crush tests within a 20-L chamber filled with 6.5% CH-air to simulate the mining hazard. Results indicate that LG Chem ICR18650S2 LiCoO cells pose a CH explosion hazard from a cell internal short circuit. Under specified test conditions, A123 Systems 26650 LiFePO cells were safer than the LG Chem ICR18650S2 LiCoO cells at a conservative statistical significance level.

摘要

美国国家职业安全与健康研究所的研究人员正在研究,在被批准可用于地下煤矿的设备中,锂离子电池因内部短路而发生热失控的可能性。研究人员使用塑料楔子引发内部短路,以评估热失控敏感性,结果证明,对于选定的锂离子电池来说,这是一种比平板法更严格的测试。研究人员在一个装有6.5%甲烷 - 空气的20升试验箱内进行电池挤压试验,以模拟采矿危险。结果表明,LG化学ICR18650S2钴酸锂电池因电池内部短路会造成甲烷爆炸危险。在特定测试条件下,在具有保守统计显著性水平的情况下,A123系统26650磷酸铁锂电池比LG化学ICR18650S2钴酸锂电池更安全。

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本文引用的文献

1
Thermal explosion hazards on 18650 lithium ion batteries with a VSP2 adiabatic calorimeter.
J Hazard Mater. 2011 Aug 15;192(1):99-107. doi: 10.1016/j.jhazmat.2011.04.097. Epub 2011 May 4.

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