Ma Zhichao, Guo Jinhong, Liu Yan Jun, Ai Ye
Pillar of Engineering Product Development, Singapore University of Technology and Design, Singapore 487372, Singapore.
Nanoscale. 2015 Sep 7;7(33):14047-54. doi: 10.1039/c5nr04272k. Epub 2015 Aug 4.
In this study, we present a simple technique capable of assembling and patterning suspended CNTs using a standing surface acoustic wave (SSAW) field. Individual CNTs could be assembled into larger CNT bundles and patterned in periodic positions on a substrate surface. The mechanism of the SSAW-based patterning technique has been investigated using both numerical simulation and experimental study. It has been found that the acoustic radiation effect due to the acoustic pressure field and the dielectrophoretic (DEP) effect induced by the electric field co-existing in the patterning process however play different roles depending on the properties of the suspended particles and the suspension medium. In the SSAW-based patterning of highly conductive CNTs with high aspect ratio geometry, the positive DEP effect dominates over the acoustic radiation effect. In contrast, the acoustic radiation effect dominates over the DEP effect when manipulating less conductive, spherical or low aspect ratio particles or biological cells. These results provide a meaningful insight into the mechanism of SSAW-based patterning, which is of great help to guide the effective use of this patterning technique for various applications.
在本研究中,我们展示了一种简单的技术,该技术能够利用驻表面声波(SSAW)场来组装悬浮的碳纳米管并对其进行图案化。单个碳纳米管可以组装成更大的碳纳米管束,并在基板表面的周期性位置进行图案化。基于SSAW的图案化技术的机制已通过数值模拟和实验研究进行了探究。已经发现,在图案化过程中,由于声压场产生的声辐射效应以及电场诱导的介电泳(DEP)效应,会根据悬浮颗粒和悬浮介质的性质而发挥不同的作用。在对具有高纵横比几何形状的高导电性碳纳米管进行基于SSAW的图案化时,正DEP效应比声辐射效应更占主导。相反,在操纵导电性较低的球形或低纵横比颗粒或生物细胞时,声辐射效应比DEP效应更占主导。这些结果为基于SSAW的图案化机制提供了有意义的见解,这对于指导该图案化技术在各种应用中的有效使用有很大帮助。