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中国安徽农村室内灰尘中重金属的污染分布及健康风险评估

Pollution distribution and health risk assessment of heavy metals in indoor dust in Anhui rural, China.

作者信息

Lin Yuesheng, Fang Fengman, Wang Fei, Xu Minglu

机构信息

College of Live Sciences, Anhui Normal University, Wuhu, 241000, China.

出版信息

Environ Monit Assess. 2015 Sep;187(9):565. doi: 10.1007/s10661-015-4763-4. Epub 2015 Aug 12.

Abstract

Zn, Pb, Cu, Cr, V, Ni, Co, and As concentrations of indoor dust in Anhui rural were determined by inductively coupled plasma-optical emission spectroscopy (ICP-OES). The degrees of metal pollution in indoor dust ranked as follows: Zn > Pb > Cr > Cu > V > Ni > Co > As, on average. The arithmetic means of Zn, Pb, Cu, Cr, V, Ni, Co, and As were 427.17, 348.73, 107.05, 113.68, 52.64, 38.93, 10.29, and 4.46 mg/kg, respectively. These were higher than background values of Anhui soil for Zn, Pb, Cu, Cr, and Ni, especially for Pb with the mean value of 13.21 times the background value. Heavy metal concentrations of indoor dust were different from different rural areas. House type (bungalows or storied house), sweeping frequency, and external environment around the house (such as the road grade) affected heavy metal concentrations in indoor dust. The results of factor analysis and correlation analysis indicated that Cu, Cr, Ni, Zn, and Co concentrations were mainly due to interior paint, metal objects, and building materials. Pb and As concentrations were due to vehicle emissions. V concentration was mainly of natural source. Average daily doses for the exposure pathway of the studied heavy metals decreased in children in the following order: hand-to-mouth ingestion > dermal contact > inhalation. The non-carcinogenic risks of heavy metals ranked as Pb > V > Cr > Cu > Zn > As > Co > Ni, and the carcinogenic risks of metals decreased in the order of Cr > Co > As > Ni. The non-carcinogenic hazard indexes and carcinogenic risks of metals in indoor dust were both lower than the safe values.

摘要

采用电感耦合等离子体发射光谱法(ICP - OES)测定了安徽农村室内灰尘中锌(Zn)、铅(Pb)、铜(Cu)、铬(Cr)、钒(V)、镍(Ni)、钴(Co)和砷(As)的含量。室内灰尘中金属污染程度平均排序如下:Zn>Pb>Cr>Cu>V>Ni>Co>As。Zn、Pb、Cu、Cr、V、Ni、Co和As的算术平均值分别为427.17、348.73、107.05、113.68、52.64、38.93、10.29和4.46mg/kg。这些含量高于安徽土壤中Zn、Pb、Cu、Cr和Ni的背景值,尤其是Pb,其平均值是背景值的13.21倍。不同农村地区室内灰尘的重金属含量不同。房屋类型(平房或楼房)、清扫频率以及房屋周围的外部环境(如道路等级)会影响室内灰尘中的重金属含量。因子分析和相关分析结果表明,Cu、Cr、Ni、Zn和Co的含量主要源于室内涂料、金属物品和建筑材料。Pb和As的含量源于车辆排放。V的含量主要来自自然源。所研究重金属经儿童暴露途径的日均剂量按以下顺序降低:手口摄入>皮肤接触>吸入。重金属的非致癌风险排序为:Pb>V>Cr>Cu>Zn>As>Co>Ni,金属的致癌风险排序为:Cr>Co>As>Ni。室内灰尘中金属的非致癌危害指数和致癌风险均低于安全值。

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