铑（III）催化的唑类与炔烃的环化反应：唑并吡啶的高效合成
Rh(III)-catalyzed cyclization reaction of azoles with alkynes: efficient synthesis of azole-fused-pyridines.
作者信息
Chen Xuebing, Wu Youzhi, Xu Jinyi, Yao Hequan, Lin Aijun, Huang Yue
机构信息
State Key Laboratory of Natural Medicines, China Pharmaceutical University, Nanjing, 24 Tong Jia Xiang, 210009, P. R. China.
出版信息
Org Biomol Chem. 2015 Sep 21;13(35):9186-9. doi: 10.1039/c5ob01338k. Epub 2015 Aug 12.
PMID:26264530
Abstract
A Rh(iii)-catalyzed cyclization of azoles with alkynes has been developed. A variety of azole-fused-pyridines were obtained in good to excellent yields and regioselectivity. Both the C5 and the C4 position of azoles were suitable for the reaction.
摘要
已开发出一种铑（III）催化的唑类与炔烃的环化反应。以良好至优异的产率和区域选择性得到了多种唑并吡啶类化合物。唑类的C5和C4位均适用于该反应。
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