使用含有四（羧基苯基）卟啉基团的金属有机框架对芳基硼酸进行可见光、光氧化还原催化的氧化羟基化反应。
Visible-light, photoredox catalyzed, oxidative hydroxylation of arylboronic acids using a metal-organic framework containing tetrakis(carboxyphenyl)porphyrin groups.
作者信息
Toyao Takashi, Ueno Nana, Miyahara Kenta, Matsui Yasunori, Kim Tae-Ho, Horiuchi Yu, Ikeda Hiroshi, Matsuoka Masaya
机构信息
Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan.
Division of Mechanics and ICT Convergence Engineering, Sun Moon University, GalSan-Ri, Tangjung-Myon, Asan Chungnam 336708, Republic of Korea.
出版信息
Chem Commun (Camb). 2015 Nov 18;51(89):16103-6. doi: 10.1039/c5cc06163f.
A Zr-based metal-organic framework with tetrakis(carboxyphenyl)porphyrin groups (Zr-MOF-TCPP: MOF-525) has been utilized as a photoredox catalyst to promote oxidative hydroxylation of arylboronic acids under green LED light irradiation. Zr-MOF-TCPP displays a superior catalytic activity for this process over the corresponding homogeneous catalyst (H4TCPP).
一种带有四（羧基苯基）卟啉基团的锆基金属有机框架材料（Zr-MOF-TCPP：MOF-525）已被用作光氧化还原催化剂，以在绿色发光二极管光照下促进芳基硼酸的氧化羟基化反应。相较于相应的均相催化剂（H4TCPP），Zr-MOF-TCPP在此过程中表现出卓越的催化活性。
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