Formanuik Alasdair, Ortu Fabrizio, Beekmeyer Reece, Kerridge Andrew, Adams Ralph W, Mills David P
School of Chemistry, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK.
Dalton Trans. 2016 Feb 14;45(6):2390-3. doi: 10.1039/c5dt04528b. Epub 2016 Jan 13.
[Th(Cp'')3] (Cp'' = {C5H3(SiMe3)2-1,3}) activates P4 to give [{Th(Cp'')3}2(μ-η(1):η(1)-P4)] (1), which has an unprecedented cyclo-P4 binding mode. DFT studies were performed on a model of 1 to probe the bonding in this system.
[Th(Cp'')₃]（Cp'' = {C₅H₃(SiMe₃)₂ - 1,3}）使P₄活化生成[{Th(Cp'')₃}₂(μ - η(1):η(1)-P₄)]（1），其具有前所未有的环 - P₄结合模式。对1的模型进行了密度泛函理论（DFT）研究，以探究该体系中的键合情况。
