Saunders John E, Sanders Connor, Chen Hao, Loock Hans-Peter
Appl Opt. 2016 Feb 1;55(4):947-53. doi: 10.1364/AO.55.000947.
Using a large-angle refractometer, the refractive indices of water, methanol, acetonitrile, acetone, ethanol, formaldehyde solution, 2-propanol, hexanes, 1-propanol, 2-butanol, tetrahydrofuran, dichloromethane, 1,4-dioxane, cyclohexane, N,N-dimethylformamide, ethylene glycol, N,N-dimethylacetamide, chloroform, glycerol, trichloroethylene, dimethylsulfoxide, p-xylene, ethylbenzene, toluene, m-xylene, benzene, and o-xylene were measured at 1550 nm and compared to literature values. In addition, the refractive indices of 48 aqueous sucrose solutions, 34 aqueous sodium chloride solutions, 40 DMSO-water, 40 ethylene glycol-water, and 40 glycerol-water mixtures were also measured at different concentrations and fit with third-order polynomial expressions. This study provides near-infrared refractive indices that were not previously available and may help with the calibration of refractive index sensors that operate at or near 1550 nm.
使用大角度折射仪,在1550纳米处测量了水、甲醇、乙腈、丙酮、乙醇、甲醛溶液、2-丙醇、己烷、1-丙醇、2-丁醇、四氢呋喃、二氯甲烷、1,4-二氧六环、环己烷、N,N-二甲基甲酰胺、乙二醇、N,N-二甲基乙酰胺、氯仿、甘油、三氯乙烯、二甲基亚砜、对二甲苯、乙苯、甲苯、间二甲苯、苯和邻二甲苯的折射率,并与文献值进行了比较。此外,还测量了48种不同浓度的蔗糖水溶液、34种不同浓度的氯化钠水溶液、40种不同浓度的二甲基亚砜-水混合物、40种不同浓度的乙二醇-水混合物和40种不同浓度的甘油-水混合物的折射率,并拟合为三阶多项式表达式。本研究提供了以前未有的近红外折射率,可能有助于校准在1550纳米或其附近工作的折射率传感器。