Lou Zheng, Li Ludong, Shen Guozhen
State Key Laboratory for Superlattices and Microstructures, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, China.
Nanoscale. 2016 Mar 7;8(9):5219-25. doi: 10.1039/c5nr08792a.
One-dimensional (1D) semiconducting heterostructures have been widely studied for optoelectronics applications because of their unique geometry and attractive physical properties. In this study, we successfully synthesized 1D ZnS/CdS heterostructures, which can be used to fabricate high performance ultraviolet/visible photodetectors. Due to the separation of photo-generated electron-hole pairs, the resultant photodetector showed excellent photoresponse properties, including ultrahigh Ion/Ioff ratios (up to 10(5)) and specific detectivity (2.23 × 10(14) Jones), relatively fast response speed (5 ms), good stability and reproducibility. Moreover, the as-fabricated flexible photodetectors showed great mechanical stability under different bending conditions. Our results revealed the possibility of 1D ZnS/CdS heterostructures for application in the detection of UV and visible light. The main advantages of the heterostructures have great potential application for future optoelectronic devices.
一维(1D)半导体异质结构因其独特的几何结构和吸引人的物理性质而在光电子应用中得到了广泛研究。在本研究中,我们成功合成了一维ZnS/CdS异质结构,其可用于制造高性能紫外/可见光探测器。由于光生电子-空穴对的分离,所得探测器表现出优异的光响应特性,包括超高的开/关电流比(高达10⁵)和比探测率(2.23×10¹⁴琼斯)、相对较快的响应速度(5毫秒)、良好的稳定性和可重复性。此外,所制备的柔性探测器在不同弯曲条件下表现出极大的机械稳定性。我们的结果揭示了一维ZnS/CdS异质结构在紫外和可见光检测中应用的可能性。这些异质结构的主要优点对未来光电器件具有巨大的潜在应用价值。