Hong Wei, Wang Jin, Wang Erkang
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, Jilin, China and University of Chinese Academy of Sciences, Beijing, 100039, China.
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, Jilin, China and Department of Chemistry and Physics, State University of New York at Stony Brook, New York, NY 11794-3400, USA.
Nanoscale. 2016 Mar 7;8(9):4927-32. doi: 10.1039/c5nr07516e.
In this research, we developed an easy way to generate CuM (M = Pd, Pt and PdPt) ultrathin nanowire networks by simply injecting the metallic precursors into an aqueous solution which contained sodium borohydride under vigorous stirring. The reaction can be finished quickly without needing any other reagents, thus leaving the products with a clean surface. The prepared materials show an ultrathin diameter of less than 5 nanometers. The reaction can be easily amplified, resulting in scalable products. These properties combined with the superior catalytic performance of the prepared CuM nanowire networks underpin their potential use in glycerol electrooxidation reaction.
在本研究中，我们开发了一种简便的方法来制备CuM（M = Pd、Pt和PdPt）超薄纳米线网络，即只需在剧烈搅拌下将金属前驱体注入含有硼氢化钠的水溶液中。该反应无需任何其他试剂即可快速完成，从而使产物表面洁净。所制备的材料显示出小于5纳米的超薄直径。该反应易于放大，可得到可扩展的产物。这些特性与所制备的CuM纳米线网络的优异催化性能相结合，支撑了它们在甘油电氧化反应中的潜在应用。
