Maeda Hiroaki, Sakamoto Ryota, Nishihara Hiroshi
Department of Chemistry, School of Science, The University of Tokyo , 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
JST-PRESTO, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan.
Langmuir. 2016 Mar 22;32(11):2527-38. doi: 10.1021/acs.langmuir.6b00156. Epub 2016 Mar 7.
Since the discovery of graphene, two-dimensional materials with atomic thickness have attracted much attention because of their characteristic physical and chemical properties. Recently, coordination nanosheets (CONASHs) came into the world as new series of two-dimensional frameworks, which can show various functions based on metal complexes formed by numerous combinations of metal ions and ligands. This Feature Article provides an overview of recent progress in synthesizing CONASHs and in elucidating their intriguing electrical, sensing, and catalytic properties. We also review recent theoretical studies on the prediction of the unique electronic structures, magnetism, and catalytic ability of materials based on CONASHs. Future prospects for applying CONASHs to novel applications are also discussed.
自从石墨烯被发现以来，具有原子厚度的二维材料因其独特的物理和化学性质而备受关注。最近，配位纳米片（CONASHs）作为一系列新型二维框架问世，它可以基于由金属离子和配体的多种组合形成的金属配合物展现出各种功能。这篇专题文章概述了在合成CONASHs以及阐明其引人入胜的电学、传感和催化性质方面的最新进展。我们还回顾了最近基于CONASHs对材料独特电子结构、磁性和催化能力预测的理论研究。此外，还讨论了将CONASHs应用于新型应用的未来前景。
