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柔性衬底上的高效单结砷化镓薄膜太阳能电池。

Highly efficient single-junction GaAs thin-film solar cell on flexible substrate.

作者信息

Moon Sunghyun, Kim Kangho, Kim Youngjo, Heo Junseok, Lee Jaejin

机构信息

Department of Electrical and Computer Engineering, Ajou University, Suwon 443-749, Republic of Korea.

出版信息

Sci Rep. 2016 Jul 20;6:30107. doi: 10.1038/srep30107.

Abstract

There has been much interest in developing a thin-film solar cell because it is lightweight and flexible. The GaAs thin-film solar cell is a top contender in the thin-film solar cell market in that it has a high power conversion efficiency (PCE) compared to that of other thin-film solar cells. There are two common structures for the GaAs solar cell: n (emitter)-on-p (base) and p-on-n. The former performs better due to its high collection efficiency because the electron diffusion length of the p-type base region is much longer than the hole diffusion length of the n-type base region. However, it has been limited to fabricate highly efficient n-on-p single-junction GaAs thin film solar cell on a flexible substrate due to technical obstacles. We investigated a simple and fast epitaxial lift-off (ELO) method that uses a stress originating from a Cr/Au bilayer on a 125-μm-thick flexible substrate. A metal combination of AuBe/Pt/Au is employed as a new p-type ohmic contact with which an n-on-p single-junction GaAs thin-film solar cell on flexible substrate was successfully fabricated. The PCE of the fabricated single-junction GaAs thin-film solar cells reached 22.08% under air mass 1.5 global illumination.

摘要

由于薄膜太阳能电池重量轻且具有柔韧性,人们对其开发一直很感兴趣。砷化镓薄膜太阳能电池是薄膜太阳能电池市场上的有力竞争者,因为与其他薄膜太阳能电池相比,它具有较高的功率转换效率(PCE)。砷化镓太阳能电池有两种常见结构:n(发射极)-on-p(基极)和p-on-n。前者表现更好,因为其收集效率高,这是由于p型基极区的电子扩散长度远长于n型基极区的空穴扩散长度。然而,由于技术障碍,在柔性衬底上制造高效的n-on-p单结砷化镓薄膜太阳能电池受到限制。我们研究了一种简单快速的外延剥离(ELO)方法,该方法利用了125μm厚的柔性衬底上Cr/Au双层产生的应力。采用AuBe/Pt/Au金属组合作为新型p型欧姆接触,成功制备了柔性衬底上的n-on-p单结砷化镓薄膜太阳能电池。在空气质量1.5全球光照条件下,制备的单结砷化镓薄膜太阳能电池的功率转换效率达到22.08%。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6376/4951801/ffacba325e27/srep30107-f1.jpg

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