锰、铁和钴催化的烯烃自由基氢官能化反应
Mn-, Fe-, and Co-Catalyzed Radical Hydrofunctionalizations of Olefins.
作者信息
Crossley Steven W M, Obradors Carla, Martinez Ruben M, Shenvi Ryan A
机构信息
Department of Chemistry, The Scripps Research Institute , La Jolla, California 92037, United States.
出版信息
Chem Rev. 2016 Aug 10;116(15):8912-9000. doi: 10.1021/acs.chemrev.6b00334. Epub 2016 Jul 27.
Abstract
Cofactor-mimetic aerobic oxidation has conceptually merged with catalysis of syngas reactions to form a wide range of Markovnikov-selective olefin radical hydrofunctionalizations. We cover the development of the field and review contributions to reaction invention, mechanism, and application to complex molecule synthesis. We also provide a mechanistic framework for understanding this compendium of radical reactions.
摘要
辅因子模拟需氧氧化在概念上已与合成气反应的催化相结合，形成了多种马氏选择性烯烃自由基氢官能团化反应。我们介绍了该领域的发展，并综述了在反应发明、机理以及在复杂分子合成中的应用方面所做的贡献。我们还提供了一个机理框架，用于理解这一系列自由基反应。
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