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功率超声对蓝莓中矢车菊素 -3-葡萄糖苷稳定性的影响。

Effects of Power Ultrasound on Stability of Cyanidin-3-glucoside Obtained from Blueberry.

作者信息

Yao Guang-Long, Ma Xing-Hui, Cao Xian-Yin, Chen Jian

机构信息

College of Food Science and Technology, Hainan University, Haikou 570228, China.

出版信息

Molecules. 2016 Nov 18;21(11):1564. doi: 10.3390/molecules21111564.

Abstract

Power ultrasound (US) could potentially be used in the food industry in the future. However, the extent of anthocyanin degradation by US requires investigation. Cyanidin-3-glucoside (Cy-3-glu) obtained from blueberry extracts was used as research material to investigate the effect of power ultrasound on food processing of anthocyanin-rich raw materials. The effects of ultrasonic waves on the stability of Cy-3-glu and on the corresponding changes in UV-Vis spectrum and antioxidant activity were investigated, and the mechanisms of anthocyanin degradation induced by ultrasonic waves were discussed. To explore Cy-3-glu degradation in different environments, we kept the Cy-3-glu solution treated with ultrasonic waves in four concentrations (0%, 10%, 20%, and 50%) of ethanol aqueous solutions to simulate water, beer, wine, and liquor storage environment according to the chemical kinetics method. Results show that the basic spectral characteristics of Cy-3-glu did not significantly change after power ultrasound cell crusher application at 30 °C. However, with anthocyanin degradation, the intensity of the peak for Cy-3-glu at 504 nm significantly decreased ( < 0.05). The degradation kinetics of Cy-3-glu by ultrasonic waves (200-500 W frequency) fitted well to first-order reaction kinetics, and the degradation rate constant of Cy-3-glu under power ultrasound was considerably larger than that under thermal degradation ( < 0.05). The sensitivity of the anthocyanins of blueberry to temperature increased with increasing ethanol concentration, and the longest half-life was observed in 20% ethanol aqueous solution.

摘要

功率超声(US)未来有可能应用于食品工业。然而,超声导致花青素降解的程度需要进行研究。从蓝莓提取物中获得的矢车菊素 - 3 - 葡萄糖苷(Cy - 3 - glu)被用作研究材料,以探究功率超声对富含花青素的原材料食品加工的影响。研究了超声波对Cy - 3 - glu稳定性、紫外 - 可见光谱相应变化以及抗氧化活性的影响,并探讨了超声波诱导花青素降解的机制。为了探索Cy - 3 - glu在不同环境中的降解情况,我们根据化学动力学方法,将经超声波处理的Cy - 3 - glu溶液置于四种浓度(0%、10%、20%和50%)的乙醇水溶液中,以模拟水、啤酒、葡萄酒和白酒的储存环境。结果表明,在30℃下应用功率超声细胞破碎仪后,Cy - 3 - glu的基本光谱特征没有显著变化。然而,随着花青素的降解,Cy - 3 - glu在504 nm处的峰强度显著降低(<0.05)。超声波(频率200 - 500 W)对Cy - 3 - glu的降解动力学很好地符合一级反应动力学,功率超声作用下Cy - 3 - glu的降解速率常数明显大于热降解时的降解速率常数(<0.05)。蓝莓花青素对温度的敏感性随乙醇浓度的增加而增加,在20%乙醇水溶液中观察到最长的半衰期。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0625/6273004/e939218d9c54/molecules-21-01564-g001.jpg

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