• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

席夫碱和冠醚作为电位型膜传感器构建中的超分子传感材料。

Schiff's Bases and Crown Ethers as Supramolecular Sensing Materials in the Construction of Potentiometric Membrane Sensors.

作者信息

Faridbod Farnoush, Ganjali Mohammad Reza, Dinarvand Rassoul, Norouzi Parviz, Riahi Siavash

机构信息

Center of Excellence in Electrochemistry, Faculty of Chemistry, University of Tehran, Tehran, Iran.

Medical Nanotechnology Research Centre, Medical Sciences/University of Tehran, Tehran, P.O. Box 14155-6451, Iran.

出版信息

Sensors (Basel). 2008 Mar 11;8(3):1645-1703. doi: 10.3390/s8031645.

DOI:10.3390/s8031645
PMID:27879786
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3663017/
Abstract

Ionophore incorporated PVC membrane sensors are well-established analyticaltools routinely used for the selective and direct measurement of a wide variety of differentions in complex biological and environmental samples. Potentiometric sensors have someoutstanding advantages including simple design and operation, wide linear dynamic range,relatively fast response and rational selectivity. The vital component of such plasticizedPVC members is the ionophore involved, defining the selectivity of the electrodes' complexformation. Molecular recognition causes the formation of many different supramolecules.Different types of supramolecules, like calixarenes, cyclodextrins and podands, have beenused as a sensing material in the construction of ion selective sensors. Schiff's bases andcrown ethers, which feature prominently in supramolecular chemistry, can be used assensing materials in the construction of potentiometric ion selective electrodes. Up to now,more than 200 potentiometric membrane sensors for cations and anions based on Schiff's bases and crown ethers have been reported. In this review cation binding and anioncomplexes will be described. Liquid membrane sensors based on Schiff's bases and crownethers will then be discussed.

摘要

掺入离子载体的聚氯乙烯（PVC）膜传感器是成熟的分析工具，常用于对复杂生物和环境样品中的多种不同离子进行选择性直接测量。电位传感器具有一些突出优点，包括设计和操作简单、线性动态范围宽、响应相对较快以及选择性合理。这种增塑PVC膜的关键成分是所涉及的离子载体，它决定了电极络合物形成的选择性。分子识别导致形成许多不同的超分子。不同类型的超分子，如杯芳烃、环糊精和开链冠醚，已被用作构建离子选择性传感器的传感材料。在超分子化学中具有突出地位的席夫碱和冠醚，可作为构建电位离子选择性电极的传感材料。到目前为止，已经报道了200多种基于席夫碱和冠醚的阳离子和阴离子电位膜传感器。在这篇综述中，将描述阳离子结合和阴离子络合物。然后将讨论基于席夫碱和冠醚的液膜传感器。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/5e07b7c50e87/sensors-08-01645f28.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/e9895b46f714/sensors-08-01645f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/8b7ec15b850e/sensors-08-01645f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/adb0f24c26ab/sensors-08-01645f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/35f0416ac1da/sensors-08-01645f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/49fd244a064b/sensors-08-01645f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/f83e5559c5b9/sensors-08-01645f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/cb516cc79b57/sensors-08-01645f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/229240603ad1/sensors-08-01645f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/5f516f493982/sensors-08-01645f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/13a39ac8bc10/sensors-08-01645f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/1c44bea04d25/sensors-08-01645f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/b0ad9f0d13ba/sensors-08-01645f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/c84706b4bb0a/sensors-08-01645f13.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/fdd6e1d51e81/sensors-08-01645f14.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/30592f275ebf/sensors-08-01645f15.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/649863e9a0bf/sensors-08-01645f16.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/3221f162dd44/sensors-08-01645f17.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/95244a894e7d/sensors-08-01645f18.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/b911f39138bc/sensors-08-01645f19.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/444735ed9023/sensors-08-01645f20.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/5adfad151b39/sensors-08-01645f21.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/c25ad7821bdd/sensors-08-01645f22.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/7b5458db1292/sensors-08-01645f23.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/8a108ade43ea/sensors-08-01645f24.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/2cb47961ca49/sensors-08-01645f25.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/03eb9033494e/sensors-08-01645f26.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/a78646919796/sensors-08-01645f27.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/5e07b7c50e87/sensors-08-01645f28.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/e9895b46f714/sensors-08-01645f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/8b7ec15b850e/sensors-08-01645f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/adb0f24c26ab/sensors-08-01645f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/35f0416ac1da/sensors-08-01645f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/49fd244a064b/sensors-08-01645f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/f83e5559c5b9/sensors-08-01645f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/cb516cc79b57/sensors-08-01645f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/229240603ad1/sensors-08-01645f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/5f516f493982/sensors-08-01645f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/13a39ac8bc10/sensors-08-01645f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/1c44bea04d25/sensors-08-01645f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/b0ad9f0d13ba/sensors-08-01645f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/c84706b4bb0a/sensors-08-01645f13.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/fdd6e1d51e81/sensors-08-01645f14.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/30592f275ebf/sensors-08-01645f15.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/649863e9a0bf/sensors-08-01645f16.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/3221f162dd44/sensors-08-01645f17.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/95244a894e7d/sensors-08-01645f18.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/b911f39138bc/sensors-08-01645f19.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/444735ed9023/sensors-08-01645f20.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/5adfad151b39/sensors-08-01645f21.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/c25ad7821bdd/sensors-08-01645f22.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/7b5458db1292/sensors-08-01645f23.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/8a108ade43ea/sensors-08-01645f24.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/2cb47961ca49/sensors-08-01645f25.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/03eb9033494e/sensors-08-01645f26.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/a78646919796/sensors-08-01645f27.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28ca/3663017/5e07b7c50e87/sensors-08-01645f28.jpg

相似文献

1
Schiff's Bases and Crown Ethers as Supramolecular Sensing Materials in the Construction of Potentiometric Membrane Sensors.席夫碱和冠醚作为电位型膜传感器构建中的超分子传感材料。
Sensors (Basel). 2008 Mar 11;8(3):1645-1703. doi: 10.3390/s8031645.
2
Sulfate-selective PVC membrane electrode based on a strontium Schiff's base complex.基于锶席夫碱配合物的硫酸根选择性聚氯乙烯膜电极。
Ann Chim. 2003 Jul-Aug;93(7-8):679-90.
3
Comparative studies of praseodymium(III) selective sensors based on newly synthesized Schiff's bases.基于新合成的希夫碱的镨（III）选择性传感器的比较研究。
Anal Chim Acta. 2009 Oct 27;653(2):161-6. doi: 10.1016/j.aca.2009.09.008. Epub 2009 Sep 9.
4
Development of Chromium(III) Selective Potentiometric Sensors for Its Determination in Petroleum Water Samples Using Synthesized Nano Schiff Base Complex as an Ionophore.以合成的纳米席夫碱配合物为离子载体的铬（III）选择性电位传感器的研制及其在石油水样中的测定
J AOAC Int. 2022 Apr 27;105(3):727-738. doi: 10.1093/jaoacint/qsab166.
5
Comparative evaluation of Dy(III) selective poly(vinyl) chloride based membrane electrodes of macrocyclic tetraimine Schiff's bases.基于大环四亚胺席夫碱的镝（III）选择性聚氯乙烯膜电极的比较评价
Talanta. 2009 Jul 15;79(2):528-33. doi: 10.1016/j.talanta.2009.04.019. Epub 2009 Apr 18.
6
From Molecular and Emulsified Ion Sensors to Membrane Electrodes: Molecular and Mechanistic Sensor Design.从分子和乳化离子传感器到膜电极：分子和机制传感器设计。
Acc Chem Res. 2019 May 21;52(5):1400-1408. doi: 10.1021/acs.accounts.9b00056. Epub 2019 Apr 24.
7
Potentiometric determination of dopamine in pharmaceutical preparations by crown ether-PVC membrane sensors.冠醚 - 聚氯乙烯膜传感器电位法测定药物制剂中的多巴胺
Anal Sci. 2004 Apr;20(4):651-5. doi: 10.2116/analsci.20.651.
8
Development of a pH sensing membrane electrode based on a new calix[4]arene derivative.基于新型杯[4]芳烃衍生物的pH传感膜电极的研制。
Talanta. 2015 Jan;132:669-75. doi: 10.1016/j.talanta.2014.10.032. Epub 2014 Oct 22.
9
Stimuli-responsive host-guest systems based on the recognition of cryptands by organic guests.基于有机客体对穴醚的识别的刺激响应主体-客体体系。
Acc Chem Res. 2014 Jul 15;47(7):1995-2005. doi: 10.1021/ar500046r. Epub 2014 May 8.
10
Antiglycation Activity of Triazole Schiff's Bases Against Fructosemediated Glycation: In Vitro and In Silico Study.三氮唑席夫碱类化合物抗果糖介导糖化的抗糖化活性：体外和计算研究。
Med Chem. 2020;16(4):575-591. doi: 10.2174/1573406415666190212105718.

引用本文的文献

1
β-cyclodextrin cross-linked metal organic frameworks as a new sensing candidate for donepezil hydrochloride potentiometric sensors.β-环糊精交联金属有机框架作为盐酸多奈哌齐电位传感器的新型传感候选材料。
BMC Chem. 2025 May 29;19(1):150. doi: 10.1186/s13065-025-01521-2.
2
Utilization of a TiO-CuO Bimetallic/Polyaniline Nanocomposite as a Transducer in a Solid Contact Potentiometric Sensor for the Determination of Vildagliptin.二氧化钛-氧化铜双金属/聚苯胺纳米复合材料在用于测定维格列汀的固体接触电位传感器中作为换能器的应用。
Polymers (Basel). 2023 Oct 4;15(19):3991. doi: 10.3390/polym15193991.
3
Homo- and Hetero-Oligonuclear Complexes of Platinum Group Metals (PGM) Coordinated by Imine Schiff Base Ligands.

本文引用的文献

1
Lanthanide Recognition: an Asymetric Erbium Microsensor Based on a Hydrazone Derivative.镧系元素识别：一种基于腙衍生物的不对称铒微传感器。
Sensors (Basel). 2007 Dec 5;7(12):3119-3135. doi: 10.3390/s7123119.
2
Aromatic Base Stacking in DNA: From ab initio Calculations to Molecular Dynamics Simulations.DNA中的芳香碱基堆积：从从头算计算到分子动力学模拟
J Biomol Struct Dyn. 2000;17 Suppl 1:1-24. doi: 10.1080/07391102.2000.10506597.
3
Strontium-selective membrane electrodes based on some recently synthesized benzo-substituted macrocyclic diamides.
偕同和杂核铂族金属（PGM）配合物的亚胺席夫碱配体。
Int J Mol Sci. 2020 May 15;21(10):3493. doi: 10.3390/ijms21103493.
4
Exploring ion-ion preferences through structure-property correlations: amino acid-derived, bis(guanidinium) disiloxane salts.通过结构-性质相关性探索离子-离子偏好：氨基酸衍生的双（胍基）二硅氧烷盐。
Sci Rep. 2020 Jan 20;10(1):646. doi: 10.1038/s41598-020-57539-0.
5
Global trends in nanomedicine research on triple negative breast cancer: a bibliometric analysis.全球三阴性乳腺癌纳米医学研究趋势：文献计量分析。
Int J Nanomedicine. 2018 Apr 17;13:2321-2336. doi: 10.2147/IJN.S164355. eCollection 2018.
6
Recent Progress in Electrochemical Biosensors for Glycoproteins.用于糖蛋白的电化学生物传感器的最新进展。
Sensors (Basel). 2016 Dec 1;16(12):2045. doi: 10.3390/s16122045.
7
Developments in the Field of Conducting and Non-conducting Polymer Based Potentiometric Membrane Sensors for Ions Over the Past Decade.过去十年中基于导电和非导电聚合物的离子电位膜传感器领域的发展
Sensors (Basel). 2008 Apr 3;8(4):2331-2412. doi: 10.3390/s8042331.
8
Crystal structure of 2-{[2-meth-oxy-5-(tri-fluoro-meth-yl)phen-yl]iminomethyl}-4-nitro-phenol.2-{[2-甲氧基-5-(三氟甲基)苯基]亚氨基甲基}-4-硝基苯酚的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Jun 13;71(Pt 7):o466-7. doi: 10.1107/S2056989015010129. eCollection 2015 Jul 1.
9
Design and Synthesis of a Pyridine Based Chemosensor: Highly Selective Fluorescent Probe For Pb.基于吡啶的化学传感器的设计与合成：用于铅的高选择性荧光探针
J Fluoresc. 2013 Aug 20. doi: 10.1007/s10895-013-1287-6.
10
2-{[3-Chloro-4-(4-chloro-phen-oxy)phen-yl]imino-meth-yl}-4-nitro-phenol.2-{[3-氯-4-(4-氯苯氧基)苯基]亚氨基甲基}-4-硝基苯酚
Acta Crystallogr Sect E Struct Rep Online. 2013 May 15;69(Pt 6):o889. doi: 10.1107/S1600536813012518. Print 2013 Jun 1.
基于一些最近合成的苯并取代大环二酰胺的锶选择性膜电极。
Anal Chem. 1999 Nov 1;71(21):4938-43. doi: 10.1021/ac990167e.
4
Highly selective and sensitive copper membrane electrode based on a new synthesized Schiff base.基于新合成席夫碱的高选择性和高灵敏度铜膜电极。
Talanta. 2007 Sep 30;73(3):553-60. doi: 10.1016/j.talanta.2007.04.010. Epub 2007 Apr 22.
5
Manganese (II) selective PVC based membrane sensor using a Schiff base.使用席夫碱的基于聚氯乙烯的锰（II）选择性膜传感器。
Talanta. 2007 Apr 15;72(1):49-53. doi: 10.1016/j.talanta.2006.09.030. Epub 2006 Nov 13.
6
Highly selective thiocyanate membrane electrode based on butane-2,3-dione bis(salicylhydrazonato)zinc(II) complex.基于丁二酮双（水杨酰腙）锌（II）配合物的高选择性硫氰酸根离子膜电极。
Talanta. 2005 May 15;66(4):837-43. doi: 10.1016/j.talanta.2004.12.039. Epub 2005 Jan 26.
7
A lead(II)-selective PVC membrane based on a Schiff base complex of N,N'-bis(salicylidene)-2,6-pyridinediamine.一种基于N,N'-双（水杨醛）-2,6-吡啶二胺席夫碱配合物的铅（II）选择性PVC膜。
Talanta. 2005 Jan 30;65(2):543-8. doi: 10.1016/j.talanta.2004.07.016.
8
A novel ion selective membrane potentiometric sensor for direct determination of Fe(III) in the presence of Fe(II).一种用于在Fe(II)存在下直接测定Fe(III)的新型离子选择性膜电位传感器。
Talanta. 2004 Nov 15;64(4):1048-52. doi: 10.1016/j.talanta.2004.05.005.
9
Cesium ion-selective electrodes based on 1,3-alternate thiacalix[4]biscrown-6,6.基于1,3-交替硫杂杯[4]双冠醚-6,6的铯离子选择性电极。
Talanta. 2004 Nov 15;64(4):975-80. doi: 10.1016/j.talanta.2004.04.015.
10
Copper(II) selective electrochemical sensor based on Schiff Base complexes.基于席夫碱配合物的铜（II）选择性电化学传感器。
Talanta. 2004 Oct 8;64(2):313-9. doi: 10.1016/j.talanta.2004.02.020.